Many government grants are available for debt relief- the key is being able to find them. The key is to be creative. For example, using government grants to buy or start a business can enable you to put the profits from the business to work paying off your debts. The big hurdle is proving that you cannot repay the amount you owe and still maintain the same level of debt, then you may qualify for a grant to get started.

From eZineArticles.com:
When looking to pay off credit card debt, one of the most overlooked options many people have are government grants. Many people do not look into these grants because they simply do not know about them. However, the government sets aside billions each year just for this purpose, to give them away. If you are one of the millions of people who are suffering from credit card debt, you definitely want to consider applying for a grant from the government.